Causes of incomplete combustion of a fuel/air mixture (Figure 2) can include: lack of combustion air and flame chilling.
Lack of Combustion Air
When the combustion air supply to a gas burner is restricted, not enough oxygen will be present for the fuel gas (hydrocarbon fuel) to be completely oxidised (burnt) into CO2 and water vapour. Instead, the partial oxidation of the fuel gas will result in the production of carbon monoxide (CO), soot (carbon) and possibly aldehydes.
Lack of combustion air can be caused by:
- Too much fuel-gas to the burner, causing a proportional reduction in the combustion air supply
- Poor burner adjustment or ventilation of the gas appliance
- A blocked or incorrectly sized flue, reducing the amount of fresh air available for combustion
Flame Chilling
Flame chilling occurs when solid objects interfere with the inner core of the flame causing the fuel-air mixture to fall below its ignition temperature thus creating a zone of incomplete combustion.
Products of Incomplete Combustion
Carbon Monoxide (CO)
Carbon monoxide is an odourless, tasteless, invisible and toxic gas that is the result of incomplete oxidation of fuel into carbon dioxide and water vapour. Carbon monoxide is also a flammable gas and can be explosive under certain conditions.
Soot (carbon)
Incomplete combustion can produce solid particles of carbon in the flame. It is these particles of hot, glowing soot that give a flame its yellow colour. The particles cool as they escape the flame and deposit as black carbon on nearby surfaces. Many authorities regard soot as a carcinogenic (cancer causing) substance.
Aldehydes
These are a class of organic compound formed during partial or incomplete combustion. In high concentrations aldehydes are poisonous. The production of aldehydes will produce a sharp, unpleasant odour and provides a warning that it is highly likely carbon monoxide is also present.
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